755 research outputs found

    One-loop renormalisation of general N=1/2 supersymmetric gauge theory

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    We investigate the one-loop renormalisability of a general N=1/2 supersymmetric gauge theory coupled to chiral matter, and show the existence of an N=1/2 supersymmetric SU(N)xU(1) theory which is renormalisable at one loop.Comment: 30 pages, including 8 figures. Plain TeX. Uses Harvmac and eps

    One-loop renormalisation of N=1/2 supersymmetric gauge theory with a superpotential

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    We construct a superpotential for the general N=1/2 supersymmetric gauge theory coupled to chiral matter in the fundamental and adjoint representations, and investigate the one-loop renormalisability of the theories.Comment: 67 pages, including 17 figures. Plain TeX. Uses Harvmac and epsf. Combined and condensed version of hep-th/0607194 and hep-th/0607195 with some added material including in particular a generalisation of the Lunin-Rey classification of potentially divergent operator

    Renormalisation of supersymmetric gauge theory in the uneliminated component formalism

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    We show that the renormalisation of the N=1 supersymmetric gauge theory when working in the component formalism, without eliminating auxiliary fields and using a standard covariant gauge, requires a non-linear renormalisation of the auxiliary fields.Comment: 9 pages, including 4 figures. Plain TeX. Uses Harvmac and epsf; reference added and minor changes to Introductio

    A bittern (Aves: Ardeidae) from the Early Miocene of New Zealand

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    Author version made available in accordance with Publisher copyright policy

    Inhibitor regulation of tissue kallikrein activity in the synovial fluid of patients with rheumatoid athritis

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    Tissue kallikrein (TK) and 1-antitrypsin (AT)/TK complexes can be detected in SF from patients with RA if components of the fluids which interfere with the detection of TK are removed. 2-Macroglobulin (2-M) in SF was demonstrated to contain trapped proteases which were still active in amidase assays. Removal of 2-M from RA SF reduced their amidase activity. However, at least some of the remaining activity was due to TK because it was soya bean trypsin inhibitor resistant and trasylol sensitive and was partly removed by affinity chromatography on anti-TK sepharose. Removal of RF from the fluids reduced the values obtained for TK levels by ELISA. Addition of SF to human urinary kallikrein (HUK) considerably reduced the levels of TK detected suggesting the presence of a TK ELISA inhibitor in the fluids. Removal of components of >300 kDa from SF markedly reduced the TK ELISA inhibitory activity and increased the values for both the TK and l-AT/TK levels in fluids as measured by ELISA. It is considered this novel inhibitor does not bind to the active site of TK but rather binds to the site reactive with anti-TK antibodies

    Miocene fossils show that kiwi (Apteryx, Apterygidae) are probably not phyletic dwarves

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    Copyright 2013 © Verlag Naturhistorisches Museum. Published version of the paper reproduced here with permission from the publisher. Publisher website: http://www.nhm-wien.ac.at/Until now, kiwi (Apteryx, Apterygidae) have had no pre-Quaternary fossil record to inform on the timing of their arrival in New Zealand or on their inter-ratite relationships. Here we describe two fossils in a new genus of apterygid from Early Miocene sediments at St Bathans, Central Otago, minimally dated to 19–16 Ma. The new fossils indicate a markedly smaller and possibly volant bird, supporting a possible overwater dispersal origin to New Zealand of kiwi independent of moa. If the common ancestor of this early Miocene apterygid species and extant kiwi was similarly small and volant, then the phyletic dwarfing hypothesis to explain relatively small body size of kiwi compared with other ratites is incorrect. Apteryx includes five extant species distributed on North, South, Stewart and the nearshore islands of New Zealand. They are nocturnal, flightless and comparatively large birds, 1–3 kg, with morphological attributes that reveal an affinity with ratites, but others, such as their long bill, that differ markedly from all extant members of that clade. Although kiwi were long considered most closely related to sympatric moa (Dinornithiformes), all recent analyses of molecular data support a closer affinity to Australian ratites (Casuariidae). Usually assumed to have a vicariant origin in New Zealand (ca 80–60 Ma), a casuariid sister group relationship for kiwi, wherein the common ancestor was volant, would more easily allow a more recent arrival via overwater dispersal

    The Use of Reversible Covalent Bonding and Induced Intramolecularity to Achieve Selectivity and Rate Acceleration in Organic Reactions

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    Thesis advisor: Kian L. TanChapter 1. Catalytic directing group, I, which was designed with the ability to form a reversible covalent bond with a substrate and bind a metal, was shown to direct the hydroformylation of allylic amines. The efficient regioselective hydroformylation of a variety of 1,2-disubstituted allylic sulfonamides to form β-amino-aldehydes under mild conditions has been shown. Chapter 2. Building off of the successful application of I, enantioenriched catalytic directing group, II, was designed and synthesized. It retained the essential features to direct hydroformylation to obtain good regioselectivity while also providing a chiral environment to induce absolute stereocontrol. Under mild conditions, a variety of disubstituted olefins react to give good yields and excellent enantioselectivites. Thus, the first enantioselective reaction performed with a catalytic directing group was demonstrated. Chapter 3. A new set of organocatalysts was developed that benefits from reversible covalent bonding and induced intramolecularity. The desymmetrization of meso-1,2-diols was accomplished using organocatalyst III, which was synthesized easily and cheaply. Experimental results indicate that the selectivity and increased reactivity are a result of the ability of III to pre-organize the substrate through a reversible, covalent bond. A variety of cyclic and acylic substrates were shown to react efficiently with good enantioselectivities under mild conditions. The catalyst's ability to functionalize cis-1,2-diols selectively indicated it might be successfully applied to site selective catalysis. Thus, the selective functionalization of a secondary alcohol in the presence of a primary alcohol was developed using a combination of binding selectivity and stereoselectivity. The (S)-enantiomer forms the secondary functionalized product while the (R)-enantiomer forms the primary functionalized product with high selectivity. As the enantiomers preferentially form different functionalized products, a regiodivergent reaction on a racemic mixture resulted giving two valuable enriched products.Thesis (PhD) — Boston College, 2013.Submitted to: Boston College. Graduate School of Arts and Sciences.Discipline: Chemistry
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